A pseudo-steady state approximation for stochastic chemical kinetics
نویسندگان
چکیده
منابع مشابه
Stochastic chemical kinetics and the total quasi-steady-state assumption: application to the stochastic simulation algorithm and chemical master equation.
Recently the application of the quasi-steady-state approximation (QSSA) to the stochastic simulation algorithm (SSA) was suggested for the purpose of speeding up stochastic simulations of chemical systems that involve both relatively fast and slow chemical reactions [Rao and Arkin, J. Chem. Phys. 118, 4999 (2003)] and further work has led to the nested and slow-scale SSA. Improved numerical eff...
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where k is the rate constant. The stochastic approach to chemical kinetics is concerned with modeling chemical reactions in situations where the assumptions underlying equations of this type break down. In order to illustrate this, suppose that the reaction above is occuring in a drop of water of volume V , which contains only a very small number, say 3, of molecules of I. The kinetic equation ...
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ژورنال
عنوان ژورنال: Rocky Mountain Journal of Mathematics
سال: 1979
ISSN: 0035-7596
DOI: 10.1216/rmj-1979-9-1-51